Download PDF by J. S. Davies: Amino Acids and Peptides (SPR Amino Acids, Peptides

By J. S. Davies

ISBN-10: 0851862241

ISBN-13: 9780851862248

Expert Periodical studies offer systematic and special overview assurance of growth within the significant parts of chemical examine. Written by way of specialists of their expert fields the sequence creates a special carrier for the energetic examine chemist, delivering commonplace severe in-depth debts of development particularly parts of chemistry.

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I7' There are curious stereochemical results, viz. that cis-4hydroxypipecolic acid esters are formed when the temperature is at - 78" throughout the reaction and subsequent quenching, but trans-isomers result if the reaction mixture is allowed to warm before quenching. 175Cyclization of the ene-iminium ion derived from the (R)-2-phenylglycinol derivative (42) gives optically-pure 4-substituted pipecolic acids after routine deprotection and hydrolysis ~ t a g e s . '79 Radical cyclization (Ph3SnH-AIBN) of N-allyl-N-Boc-L-serine lactone gives 4-alkyl- and 4,4-di-alkylprolines.

L-Phenylalanine and its methyl ester, derivatized with the nitroxyl acid, yields spin label 2,2,5,5-tetramethyl-l-oxypyrroline-3-carboxylic ENDOR spectra interpreted in terms of conformational detaikV4 Electron diffraction data provide a more traditional basis for gasphase conformational information, applied to DL-alanine (a unique con) ~ ~to~ glycine (a planar structure formation for the neutral t a ~ t o m e r and with OH and NH2 groups in an a n t i - r e l a t i ~ n s h i p ) . 6 Physico-Chemical Studies What might be called 'the thermodynamic properties of wet amino acids' have obvious biological interest since that is one of the normal viewpoints taken in vivo by nearby molecules, small and large.

6 Prebiotic Synthesis Models for Amino Acids Relevant reviews of the broader topic, within which environmental synthesis of amino acids may have occurred, have been published. One'94 is aimed more at the layman than the other. 19' This reductive fixation of nitrogen is enhanced by HC1, apparently suffering oxidation to C103- in the process. 7 26 Amino Acids ~ ~ Peptides n d tives showed the highest activity. '~' Trifluoroalanine is obtainable from hexafluoroacetone or trifluoropyruvates, but conveniently from 5-fluoro-2-phenyl-4-trifluoromethyloxazole (see also Refs.

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Amino Acids and Peptides (SPR Amino Acids, Peptides (RSC))vol. 24 by J. S. Davies


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